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园艺学报 ›› 2017, Vol. 44 ›› Issue (3): 557-565.doi: 10.16420/j.issn.0513-353x.2016-0612

• 研究报告 • 上一篇    下一篇

刺槐属6种材料鲜花芳香成分分析

韩丛聪1,荀守华1,*,姜天华2,毛秀红1,郑成淑2   

  1. 1山东省林业科学研究院,济南 250014;2山东农业大学园艺科学与工程学院,山东泰安 271018
  • 出版日期:2017-03-25 发布日期:2017-03-25

Studies on Aroma Compounds of Flowers of Six Germplasm of Genus Robinia

HAN Congcong1,XUN Shouhua1,*,JIANG Tianhua2,MAO Xiuhong1,and ZHENG Chengshu2   

  1. 1Shandong Academy of ForestryJinan 250014China2College of Horticulture and Science EngineeringShandong Agricultural UniversityTai’anShandong 271018China
  • Online:2017-03-25 Published:2017-03-25

摘要:

采用顶空固相微萃取和气相色谱—质谱联用(SPME–GC–MS)技术检测了多花刺槐(Robinia neo-mexicana var. luxurians),粘枝刺槐(R. viscosa),‘紫艳青山’、‘多彩青山’、L2F和L68F刺槐(R. pseudoacacia)鲜花芳香成分。结果表明:(1)6种刺槐鲜花共检测出53种芳香成分,主要有萜烯类、醇类、酯类、酮类、醛类、芳香烃类、烷烃类;在6种刺槐鲜花所释放的芳香成分中均含有萜烯类、醇类、酯类,且相对含量均为:萜烯类 > 醇类 > 酯类,萜烯类是最主要的芳香成分。(2)开红花的多花刺槐和粘枝刺槐鲜花芳香成分相对含量最多的萜烯类、醇类分别是 (E)–4,8–二甲基–1,3,7–壬三烯、1–辛烯–3–醇,其余4种开白花的刺槐鲜花芳香成分相对含量最多的萜烯类、醇类分别是β–罗勒烯、芳樟醇。(3)根据芳香成分相对含量及种类的多少,将多花刺槐和‘多彩青山’刺槐的鲜花定为淡香型,粘枝刺槐,‘紫艳青山’、L2F和L68F刺槐定为浓香型。

关键词: 刺槐属;鲜花;芳香成分;固相微萃取;气相色谱&mdash, 质谱联用

Abstract:

Aroma components in fresh flowers from 6 germplasm of Robinia neo-mexicana var. LuxuriansR. viscosaR. pseudoacacia‘Ziyan Qingshan’,R. pseudoacacia‘Duocai Qingshan’,L2F and L68F were analyzed by Micro-extraction and GC–MS technology. The results showed that:(1)Fifty-three kinds of volatile compounds were identified in fresh flowers from 6 cultivars of genus Robinia,mainly including terpenes,alcohols,esters,ketones,aldehydes,arenes and alkanes. Flowers aromatic components of the 6 samples consist of terpenes,alcohols and esters. The relative amount of components was as follows:terpene > alcohol > esters. Terpene is the main aroma components.(2)The highest content of terpenes and alcohols of red flowers of R. neo-mexicana var. luxurians and R. viscosaare (E)-4,8- dimethylnona-1,3,7-triene, 1-octen-3-ol. The highest content of terpenes and alcohols from the rest 4 samples with white flowers are beta-ocimene,linalool.(3)According to the relative content and type of volatile matter,we defined the flowers fragrance of R. neo-mexicana var. luxurians and R. pseudoacacia ‘Duocai Qingshan’as light flavor,,R. pseudoacacia‘Ziyan Qingshan’,L2F and L68F as strong flavor. Robinia viscosa

Key words: genus Robinia;flower;aroma component;HS-SMPE;GC&ndash, MS